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Cationic Gold(I) Complexes: Highly Alkynophilic Catalysts for the exo- and endo-Cyclization of Enynes.

✍ Scribed by Cristina Nieto-Oberhuber; M. Paz Munoz; Elena Bunuel; Cristina Nevado; Diego J. Cardenas; Antonio M. Echavarren

Publisher
John Wiley and Sons
Year
2004
Weight
213 KB
Volume
35
Category
Article
ISSN
0931-7597

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Cover Picture: Cationic Gold(I) Complexe
Cover Picture: Cationic Gold(I) Complexes: Highly Alkynophilic Catalysts for the exo- and endo-Cyclization of Enynes (Angew. Chem. Int. Ed. 18/2004)
✍ Cristina Nieto-Oberhuber; M. Paz MuΓ±oz; Elena BuΓ±uel; Cristina Nevado; Diego J. πŸ“‚ Article πŸ“… 2004 πŸ› John Wiley and Sons 🌐 English βš– 20 KB πŸ‘ 1 views

**Lauding the rings** in the realm of metal‐catalyzed cyclizations, where many mechanistic shadows lie: Gold is master, particularly in reactions that proceed through metal cyclopropylcarbene intermediates. In their Communication on page 2402 ff., A. M. Echavarren and co‐workers report on their ques

ChemInform Abstract: Cationic Gold(I) Co
ChemInform Abstract: Cationic Gold(I) Complexes: Highly Efficient Catalysts for the Addition of Alcohols to Alkynes.
✍ J. H. TELES; S. BRODE; M. CHABANAS πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 29 KB πŸ‘ 2 views

1998 catalysis, phase-transfer catalysis catalysis, phase-transfer catalysis O 0020 35 -040 Cationic Gold(I) Complexes: Highly Efficient Catalysts for the Addition of Alcohols to Alkynes. -Cationic gold(I) complexes, generated in situ by reaction of [ligand-AuMe] with Lewis or Broensted acids, are e