In polymeric [Ag(C 2 F 3 O 2 )(C 26 H 24 P 2 )] n , the carboxylate is monodentate to silver, and the two diphosphine ligands that occupy different positions of 1 site symmetry link the Ag(C 2 O 2 F 3 ) units into a chain. The Ag atom shows trigonalplanar coordination.
catena-μ[1,2-Bis(diphenylphosphino)ethane]-dicyanomercury(II)
✍ Scribed by Camalli, M. ;Caruso, F. ;Zambonelli, L.
- Book ID
- 114528765
- Publisher
- International Union of Crystallography
- Year
- 1982
- Weight
- 321 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0567-7408
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📜 SIMILAR VOLUMES
Acta Cryst. (2001). E57, m433±m434 slightly longer in the THF adduct than the corresponding distances in the CH 2 Cl 2 adduct [2.141 (1) and 2.156 (1) A Ê ], but both NiÐBr bonds are very similar. In this structure, there is a stacking interaction between the THF ring and the C121Ð C126 phenyl ring,
In the title compound, [PtI~2~(C~26~H~24~P~2~)]·2CH~2~Cl~2~, the PtI~2~(dppe) [dppe = 1,2-bis(diphenylphosphino)ethane] molecules possess twofold rotation symmetry. The Pt coordination displays a square-planar arrangement, with the sum of the angles around the Pt atom being 360.01 (2)°. The Pt—I dis