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[1,2-Bis(diphenylphosphino)ethane]diiodidoplatinum(II) dichloromethane disolvate

✍ Scribed by Sivaramakrishna, Akella ;Su, Hong ;Moss, John R.

Publisher: International Union of Crystallography
Year: 2007
Tongue: English
Weight: 754 KB
Volume: 63
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536807046636

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✦ Synopsis

In the title compound, [PtI~2~(C~26~H~24~P~2~)]·2CH~2~Cl~2~, the PtI~2~(dppe) [dppe = 1,2-bis(diphenylphosphino)ethane] molecules possess twofold rotation symmetry. The Pt coordination displays a square-planar arrangement, with the sum of the angles around the Pt atom being 360.01 (2)°. The Pt—I distance is 2.6484 (5) Å. In the crystal structure, intermolecular C—H...I contacts link the PtI~2~(dppe) molecules into rows along the c axis, with a C...I distance of 3.873 (5) Å.

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