𝔖 Bobbio Scriptorium
✦   LIBER   ✦

catena-Poly[[diaqua­calcium(II)]-di-μ-2-formyl­benzoato]

✍ Scribed by Odabaşoğlu, Mustafa ;Büyükgüngör, Orhan


Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
600 KB
Volume
63
Category
Article
ISSN
1600-5368

No coin nor oath required. For personal study only.

✦ Synopsis


In the title compound, [Ca(C~8~H~5~O~3~)~2~(H~2~O)~2~]~n~, the Ca^II^ atom (site symmetry 2) is eight-coordinated by two bidentate 2-formylbenzoate ligands, two monodentate formylbenzoate ligands and two terminal water molecules. The bridging ligands result in a one-dimensional coordination polymer. A network of O—H...O hydrogen bonds links the polymeric chains.


📜 SIMILAR VOLUMES


catena-Poly[di-μ3-benzoato-tetra­-μ2-ben
✍ Liu, Xuan-Wen 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 230 KB

In the title complex, [Cd 3 (C 7 H 5 O 2 ) 6 (C 4 H 4 N) 2 ] n , the benzoate groups adopt 3 and 2 coordination modes to connect neighbouring cadmium(II) ions into one-dimensional chains. One of the Cd atoms lies on a crystallographic twofold axis.

catena-Poly[[[diaqua­calcium(II)]-di-μ-3
✍ Gao, Shan ;Ng, Seik Weng 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 212 KB

The Ca atom in the title compound, {[Ca(HO 2 CC 6 H 4 OCH 2 -CO 2 ) 2 (H 2 O) 2 ]Á2H 2 O} n , is eight-coordinate. The HO 2 CC 6 H 4 -OCH 2 CO 2 À monoanion binds in a chelating mode; it also functions as a bridge, linking adjacent Ca atoms into a zigzag chain. Hydrogen bonds link the chains into a

catena-Poly[[tri-μ2-benzoato-dizinc(II)]
✍ Yang, Shi-Yao ;Long, La-Sheng ;Huang, Rong-Bin ;Zheng, Lan-Sun ;Ng, Seik Weng 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 99 KB

Acta Cryst. (2005). E61, m1340-m1342 Yang et al. [Zn 2 (C 7 H 5 O 2 ) 3 (OH)] m1341 metal-organic papers m1342 Yang et al. [Zn 2 (C 7 H 5 O 2 ) 3 (OH)]