In the title compound, [Ca(C~8~H~5~O~3~)~2~(H~2~O)~2~]~__n__~, the Ca^II^ atom (site symmetry 2) is eight-coordinated by two bidentate 2-formylbenzoate ligands, two monodentate formylbenzoate ligands and two terminal water molecules. The bridging ligands result in a one-dimensional coordination poly
catena-Poly[[aqua(benzoato)(N,N′-dimethylformamide)calcium(II)]-μ-benzoato]
✍ Scribed by Yano, Shigenobu ;Numata, Momoko ;Kato, Masako ;Motoo, Shiro ;Nishimura, Toshio
- Publisher
- International Union of Crystallography
- Year
- 2001
- Tongue
- English
- Weight
- 279 KB
- Volume
- 57
- Category
- Article
- ISSN
- 1600-5368
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Single-crystal X-ray study T = 298 K Mean '(C±C) = 0.005 A Ê R factor = 0.054 wR factor = 0.125 Data-to-parameter ratio = 14.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the title complex, {[Cu(C 8 H 4 O 4 )(C 12 H 8 N 2 )(H 2 O)]Á-C 3 H 7 NOÁH 2 O} n , the Cu atom is surrounded by two O atoms from two isophthalate dianions, an aqua O atom and two N atoms from a phenanthroline heterocycle in a distorted square-pyramidal geometry. The isophthalate dianion function
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