In the title compound, [Ca(C~8~H~5~O~3~)~2~(H~2~O)~2~]~__n__~, the Ca^II^ atom (site symmetry 2) is eight-coordinated by two bidentate 2-formylbenzoate ligands, two monodentate formylbenzoate ligands and two terminal water molecules. The bridging ligands result in a one-dimensional coordination poly
catena-Poly[di-μ3-benzoato-tetra-μ2-benzoato-dipyrroletricadmium(II)]
✍ Scribed by Liu, Xuan-Wen
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 230 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title complex, [Cd 3 (C 7 H 5 O 2 ) 6 (C 4 H 4 N) 2 ] n , the benzoate groups adopt 3 and 2 coordination modes to connect neighbouring cadmium(II) ions into one-dimensional chains. One of the Cd atoms lies on a crystallographic twofold axis.
📜 SIMILAR VOLUMES
Acta Cryst. (2005). E61, m1340-m1342 Yang et al. [Zn 2 (C 7 H 5 O 2 ) 3 (OH)] m1341 metal-organic papers m1342 Yang et al. [Zn 2 (C 7 H 5 O 2 ) 3 (OH)]
Single-crystal X-ray study T = 295 K Mean '(C±C) = 0.005 A Ê R factor = 0.021 wR factor = 0.045 Data-to-parameter ratio = 11.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.