The title compound, [Ni(C 5 HN 2 O 4 )(C 10 H 8 N 2 )] n , is isotypic with its Co II and Zn II analogues. The asymmetric unit contains two crystallographically independent monomer units with similar geometry. The Ni II cations have a distorted octahedral environment formed by two carboxylate O atom
catena-Poly[[(2,2′-bipyridine)nickel(II)]-μ-4,4′-oxydibenzoato]
✍ Scribed by Xiao, Hong-Ping ;Cheng, Ya-Qian ;Li, Xin-Hua
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 192 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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In the title compound, {[Ni(C 14 H 8 O 5 )(C 12 H 8 N 2 )]Á0.25H 2 O} n , the Ni atom displays a distorted octahedral geometry de®ned by four carboxy O atoms from two 4,4 H -oxydibenzoate (oba) dianions and two N atoms from a 1,10-phenanthroline molecule. The V-shaped oba anion acts as a bridge betw
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In the title compound, {[Cu(C~14~H~8~O~5~)(C~14~H~8~N~4~)]·H~2~O}~__n__~, the Cu^II^ atom adopts a distorted __cis__-CuN~2~O~2~ square-planar coordination geometry. 4,4′-Oxydibenzoate (__L__) ligands link the Cu^II^ atoms, generating a helical chain. Neighbouring chains are linked through π–π intera
Single-crystal X-ray study T = 298 K Mean '(C±C) = 0.009 A Ê R factor = 0.055 wR factor = 0.135 Data-to-parameter ratio = 13.5 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.