In the title compound, {[Cu(C~14~H~8~O~5~)(C~14~H~8~N~4~)]·H~2~O}~__n__~, the Cu^II^ atom adopts a distorted __cis__-CuN~2~O~2~ square-planar coordination geometry. 4,4′-Oxydibenzoate (__L__) ligands link the Cu^II^ atoms, generating a helical chain. Neighbouring chains are linked through π–π intera
catena-Poly[[[(1,10-phenanthroline)nickel(II)]-μ-4,4′-oxydibenzoato] 0.25-hydrate]
✍ Scribed by Xiao, Hong-Ping ;Wang, Jia-Guo ;Li, Xin-Hua ;Hu, Mao-Lin ;Zhang, Wei-Bing
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 222 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title compound, {[Ni(C 14 H 8 O 5 )(C 12 H 8 N 2 )]Á0.25H 2 O} n , the Ni atom displays a distorted octahedral geometry de®ned by four carboxy O atoms from two 4,4 H -oxydibenzoate (oba) dianions and two N atoms from a 1,10-phenanthroline molecule. The V-shaped oba anion acts as a bridge between two Ni atoms in a tris-bidentate coordination mode, forming a zigzag coordination polymer.
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 295 K Mean '(C±C) = 0.003 A Ê R factor = 0.034 wR factor = 0.092 Data-to-parameter ratio = 15.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the title compound, [Pb(C~8~H~4~O~4~)(C~24~H~16~N~2~)]~__n__~, the benzene-1,4-dicarboxylate (1,4-BDC) dianions link the Pb^II^ atoms to form a chain structure. The Pb^II^ atom is coordinated by 4,7-diphenyl-1,10-phenanthroline (__L__) and is also bonded to four 1,4-BDC O atoms, resulting in a ve