catena-Poly[tris(2,2′-bipyridine)nickel(II) [hexa-μ-iodo-diplumbate(II)]]
✍ Scribed by Fan, Le-Qing ;Chen, Ling ;Wu, Li-Ming
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 114 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
The title compound, [Ni(C 5 HN 2 O 4 )(C 10 H 8 N 2 )] n , is isotypic with its Co II and Zn II analogues. The asymmetric unit contains two crystallographically independent monomer units with similar geometry. The Ni II cations have a distorted octahedral environment formed by two carboxylate O atom
Single-crystal X-ray study T = 298 K Mean '(C±C) = 0.003 A Ê R factor = 0.040 wR factor = 0.097 Data-to-parameter ratio = 14.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title hydrated 2,2 0 -bipyridine-6,6 0 -dicarboxylatecadmium(II) complex, {[Cd(C 12 H 2 N 2 O 4 )(H 2 O) 2 ]Á2H 2 O} n , crystallizes with eight oxygen-bridged monomer units in the unit cell. The divalent cadmium ion is seven-coordinate, and the coordination polyhedron can best be described as s