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catena-Poly[[(2,2-bipyridine)cobalt(II)]-μ-imidazole-4,5-dicarboxylato]

✍ Scribed by Hao, Lu-Jiang ;Bao, Zhen-Min ;Yu, Tong-Li

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
696 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title complex, [Co(C 5 HN 2 O 4 )(C 10 H 8 N 2 )] n , the asymmetric unit contains two crystallographically independent monomer units with similar geometry. The Co II cations are coordinated octahedrally by two carboxylate O atoms and by four N atoms, two of which belong to the 2,2-bipyridine ligand and two to different imidazole rings. The connectivity between the metal cations and the imidazole-4,5-carboxylate units gives rise to one-dimensional zigzag chains parallel to [010].

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