✦ LIBER ✦

catena-Poly[1-ethyl-4-methylpyridinium [argentate(I)-di-μ-iodido]]

✍ Scribed by Wang, Yun Jie ;Li, Hao Hong ;Chen, Zhi Rong ;Huang, Chang Cang ;Liu, Ji Bo

Publisher: International Union of Crystallography
Year: 2007
Tongue: English
Weight: 708 KB
Volume: 63
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536807052269

No coin nor oath required. For personal study only.

✦ Synopsis

The title compound, {(C~8~H~12~N)[AgI~2~]}~n~, was synthesized by a self-assembling reaction of 1-ethyl-4-methylpyridinium iodide and silver(I) iodide. The anion adopts a one-dimensional chain structure with the Ag atom in the chain in a nearly regular tetrahedral environment. The crystal packing is stabilized by electrostatic interactions and by a C—H...I hydrogen bond between a methylene H atom of the ethyl substituent and an I atom.

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