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Catalytic Transfer Hydrogenation with Terdentate CNN Ruthenium Complexes: The Influence of the Base

✍ Scribed by Walter Baratta; Katia Siega; Pierluigi Rigo


Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
159 KB
Volume
13
Category
Article
ISSN
0947-6539

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Fast and Chemoselective Transfer Hydroge
✍ Walter Baratta; Katia Siega; Pierluigi Rigo πŸ“‚ Article πŸ“… 2007 πŸ› John Wiley and Sons 🌐 English βš– 81 KB πŸ‘ 1 views

## Abstract Aromatic, aliphatic and Ξ±,β‐unsaturated aldehydes are quickly, quantitatively and chemoselectively reduced to primary alcohols with 2‐propanol using 0.05–0.01 mol % of the terdentate CNN ruthenium complex RuCl(CNN)(dppb) (1) [HCNN=6‐(4′‐methylphenyl)‐2‐pyridylmethylamine; dppb=Ph~2~P(CH