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Fast and Chemoselective Transfer Hydrogenation of Aldehydes Catalyzed by a Terdentate CNN Ruthenium Complex [RuCl(CNN)(dppb)].

โœ Scribed by Walter Baratta; Katia Siega; Pierluigi Rigo


Publisher
John Wiley and Sons
Year
2007
Weight
27 KB
Volume
38
Category
Article
ISSN
0931-7597

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Fast and Chemoselective Transfer Hydroge
โœ Walter Baratta; Katia Siega; Pierluigi Rigo ๐Ÿ“‚ Article ๐Ÿ“… 2007 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 81 KB ๐Ÿ‘ 1 views

## Abstract Aromatic, aliphatic and ฮฑ,ฮฒโ€unsaturated aldehydes are quickly, quantitatively and chemoselectively reduced to primary alcohols with 2โ€propanol using 0.05โ€“0.01 molโ€‰% of the terdentate CNN ruthenium complex RuCl(CNN)(dppb) (1) [HCNN=6โ€(4โ€ฒโ€methylphenyl)โ€2โ€pyridylmethylamine; dppb=Ph~2~P(CH