Fast and Chemoselective Transfer Hydroge
โ
Walter Baratta; Katia Siega; Pierluigi Rigo
๐
Article
๐
2007
๐
John Wiley and Sons
๐
English
โ 81 KB
๐ 1 views
## Abstract Aromatic, aliphatic and ฮฑ,ฮฒโunsaturated aldehydes are quickly, quantitatively and chemoselectively reduced to primary alcohols with 2โpropanol using 0.05โ0.01 molโ% of the terdentate CNN ruthenium complex RuCl(CNN)(dppb) (1) [HCNN=6โ(4โฒโmethylphenyl)โ2โpyridylmethylamine; dppb=Ph~2~P(CH