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Iron(II) Complexes for the Efficient Catalytic Asymmetric Transfer Hydrogenation of Ketones

✍ Scribed by Nils Meyer; Alan J. Lough; Robert H. Morris

Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
349 KB
Volume
15
Category
Article
ISSN
0947-6539

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Osmium Pyme Complexes for Fast Hydrogena
Osmium Pyme Complexes for Fast Hydrogenation and Asymmetric Transfer Hydrogenation of Ketones
✍ Walter Baratta; Maurizio Ballico; Alessandro Del Zotto; Katia Siega; Santo Magno 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 259 KB 👁 1 views

## Abstract The osmium compound __trans__,__cis__‐[OsCl~2~(PPh~3~)~2~(Pyme)] (1) (Pyme=1‐(pyridin‐2‐yl)methanamine), obtained from [OsCl~2~(PPh~3~)~3~] and Pyme, thermally isomerizes to __cis__,__cis__‐[OsCl~2~(PPh~3~)~2~(Pyme)] (2) in mesitylene at 150 °C. Reaction of [OsCl~2~(PPh~3~)~3~] with Ph~