𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Catalytic Mannich-type reaction of phosphorylimidates

✍ Scribed by Shū Kobayashi; Junya Nakano; Ryosuke Matsubara

Book ID
108283308
Publisher
Elsevier Science
Year
2010
Tongue
French
Weight
235 KB
Volume
66
Category
Article
ISSN
0040-4020

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Direct Catalytic Asymmetric Mannich-Type
Direct Catalytic Asymmetric Mannich-Type Reaction of Thioamides
✍ Yuta Suzuki; Ryo Yazaki; Naoya Kumagai; Masakatsu Shibasaki 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 402 KB 👁 1 views

## Abstract **Weich hilft hart**: Die Titelreaktion zwischen Thioamiden und __N__‐(Diphenylphosphinoyl)iminen nutzt die kooperative Katalyse einer weichen Lewis‐Säure und einer harten Brønsted‐Base, um Thioamid‐Kohlenstoff‐Pränucleophile in Mannich‐Produkte zu überführen (siehe Schema). Folgereakti

Direct Catalytic Asymmetric Mannich-Type
Direct Catalytic Asymmetric Mannich-Type Reaction of Thioamides
✍ Yuta Suzuki; Ryo Yazaki; Naoya Kumagai; Masakatsu Shibasaki 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 403 KB 👁 1 views

## Abstract **Taking the reins**: The title transformation of thioamides and __N__‐diphenylphosphinoyl imines is described. By harnessing the power of cooperative catalysis between a soft Lewis acid and a hard Brønsted base, thioamide carbon pronucleophiles can furnish Mannich products (see scheme)