Single-handed PQXphos, i.e., helical poly(quinoxaline-2,3-diyl)s bearing diarylphosphino pendant groups, served as remarkable chiral ligands in palladium-catalyzed asymmetric hydrosilylation of styrenes and asymmetric biaryl synthesis by Suzuki–Miyaura coupling, affording up to 98 % enantiomeric exc
✦ LIBER ✦
Catalytic asymmetric synthesis using chirality‑switchable helical polymer as a chiral ligand
✍ Scribed by Suginome, Michinori (author);Yamamoto, Takeshi (author);Nagata, Yuuya (author);Yamada, Tetsuya (author);Akai, Yuto (author)
- Book ID
- 115474803
- Publisher
- International Union of Pure and Applied Chemistry
- Year
- 2012
- Tongue
- English
- Weight
- 613 KB
- Volume
- 84
- Category
- Article
- ISSN
- 0033-4545
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