Catalytic asymmetric synthesis using chi
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Suginome, Michinori (author);Yamamoto, Takeshi (author);Nagata, Yuuya (author);Y
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Article
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2012
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International Union of Pure and Applied Chemistry
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English
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Single-handed PQXphos, i.e., helical poly(quinoxaline-2,3-diyl)s bearing diarylphosphino pendant groups, served as remarkable chiral ligands in palladium-catalyzed asymmetric hydrosilylation of styrenes and asymmetric biaryl synthesis by SuzukiโMiyaura coupling, affording up to 98 % enantiomeric exc