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ChemInform Abstract: Catalytic Asymmetric Synthesis Using Chirality-Switchable Helical Polymer as a Chiral Ligand

โœ Scribed by Suginome, Michinori; Yamamoto, Takeshi; Nagata, Yuuya; Yamada, Tetsuya; Akai, Yuto


Book ID
118755883
Publisher
John Wiley and Sons
Year
2012
Weight
18 KB
Volume
43
Category
Article
ISSN
0931-7597

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Catalytic asymmetric synthesis using chi
โœ Suginome, Michinori (author);Yamamoto, Takeshi (author);Nagata, Yuuya (author);Y ๐Ÿ“‚ Article ๐Ÿ“… 2012 ๐Ÿ› International Union of Pure and Applied Chemistry ๐ŸŒ English โš– 613 KB

Single-handed PQXphos, i.e., helical poly(quinoxaline-2,3-diyl)s bearing diarylphosphino pendant groups, served as remarkable chiral ligands in palladium-catalyzed asymmetric hydrosilylation of styrenes and asymmetric biaryl synthesis by Suzukiโ€“Miyaura coupling, affording up to 98 % enantiomeric exc