Carbonium ion rearrangements of the 3-nortricyclylcarbinyl system
โ Scribed by R.R. Sauers; J.A. Beisler
- Publisher
- Elsevier Science
- Year
- 1964
- Tongue
- French
- Weight
- 143 KB
- Volume
- 5
- Category
- Article
- ISSN
- 0040-4039
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๐ SIMILAR VOLUMES
The metastable peaks appearing in a mass spectrum give a direct measure of the kinetic energy released in the dissociation of an ion. ' Overlapping isotope peaks; the value given is a lower limit for the KE release
Tertiary alcohols with a y-silyl group (3) generally undergo a simple carbonium ion rearrangement in acid giving a single alkene product (4) with loss of the silyl group. We reported earlier several examples of carbonium ion rearrangements of the general type (1 + 2) in which the migrating group R
Formation of acyclic products in the reaction of triisobutylaluminum and 1,3,3trimethylcyclopropene can reasonably be ascribed to a carbonium ion rearrangement. This suggestion supports the mechanism for carbalumination of alkenes proposed by Eisch.