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Evidence for a carbonium ion rearrangement in the reaction of triisobutylaluminum and 1,3,3-trimethylcyclopropene

✍ Scribed by Herman G. Richey Jr.; Barry Kubala; Mark A. Smith

Publisher: Elsevier Science
Year: 1981
Tongue: French
Weight: 212 KB
Volume: 22
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)81934-1

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✦ Synopsis

Formation of acyclic products in the reaction of triisobutylaluminum and 1,3,3trimethylcyclopropene can reasonably be ascribed to a carbonium ion rearrangement. This suggestion supports the mechanism for carbalumination of alkenes proposed by Eisch.

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## Abstract For Abstract see ChemInform Abstract in Full Text.