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Anomalous Reactivity of Methylidenemalonates in the Prilezhaev Reaction. Evidence For A 1,3-Dipolar Mechanism

✍ Scribed by Christian J. C. De Cock; Jean-Luc De Keyser; Jacques H. Poupaert; Pierre Dumont


Publisher
Wiley (John Wiley & Sons)
Year
2010
Weight
150 KB
Volume
96
Category
Article
ISSN
0037-9646

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Evidence for a diradical intermediate in
✍ G. Huybrechts; B. Van Mele πŸ“‚ Article πŸ“… 1978 πŸ› John Wiley and Sons 🌐 English βš– 254 KB

Despite an extensive literature, controversy about the Diels-Alder reaction mechanism still exists. For the thermal dimerization of 1,3-butadiene, for example, a concerted one-step [I] or two-stage [2] mechanism, a mixture of orbital symmetry allowed and forbidden cycloadditions 131, as well as a tw