The direct observation of energy release in carbonium ion rearrangements
β Scribed by Dudley H. Williams; B.Jane Stapleton; Richard D. Bowen
- Publisher
- Elsevier Science
- Year
- 1978
- Tongue
- French
- Weight
- 190 KB
- Volume
- 19
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
β¦ Synopsis
The metastable peaks appearing in a mass spectrum give a direct measure of the kinetic energy released in the dissociation of an ion. ' Overlapping isotope peaks; the value given is a lower limit for the KE release
π SIMILAR VOLUMES
## Abstract The polymerization of olefins of the series (__n__β1)methylβ1βalkenes through carbonium ion intermediates appears to involve a rearrangement from a secondary to a tertiary carbonium ion. The structure of the final polymer, as determined by nuclear magnetic resonance, depends on the rela
Formation of acyclic products in the reaction of triisobutylaluminum and 1,3,3trimethylcyclopropene can reasonably be ascribed to a carbonium ion rearrangement. This suggestion supports the mechanism for carbalumination of alkenes proposed by Eisch.