Tertiary alcohols with a y-silyl group (3) generally undergo a simple carbonium ion rearrangement in acid giving a single alkene product (4) with loss of the silyl group. We reported earlier several examples of carbonium ion rearrangements of the general type (1 + 2) in which the migrating group R
β¦ LIBER β¦
Group-theoretical analysis of carbonium ion rearrangements: The barbaralyl cation
β Scribed by Thomas D. Bouman; Carl Trindle
- Publisher
- Springer
- Year
- 1975
- Tongue
- English
- Weight
- 794 KB
- Volume
- 37
- Category
- Article
- ISSN
- 1432-2234
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## Abstract The polymerization of olefins of the series (__n__β1)methylβ1βalkenes through carbonium ion intermediates appears to involve a rearrangement from a secondary to a tertiary carbonium ion. The structure of the final polymer, as determined by nuclear magnetic resonance, depends on the rela