## Abstract The ^13^C NMR spectra were determined and signals assigned to the various carbons of veratridine and cevadine.
Carbon-13 nuclear magnetic resonance spectra of methyl 2-pyronecarboxylates
✍ Scribed by Takeshi Imagawa; Akira Haneda; Mituyosi Kawanisi
- Publisher
- John Wiley and Sons
- Year
- 1980
- Tongue
- English
- Weight
- 393 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0749-1581
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✦ Synopsis
Abstract
The ^13^C NMR spectra of methyl 2‐pyrone‐3‐, 4‐, 5‐ and 6‐carboxylates were studied and the substituent effects on the 2‐pyrone ring were compared with those of some model compounds. ^1^H NMR spectra were also recorded and discussed. The long range ^13^C, ^1^H coupling constants were obtained, discussed and proved useful in signal assignments.
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REFERENCE DATA causes the electron density to be comparatively lower at C-3 and C-5 than at C-2 and C-4, so that the former signals resonate at lower fields. Distinction between the signals of the C-2/C-4 and C-3/C-5 pairs was achieved by comparing the C-H coupling patterns of 5 and 1. Compounds 1,