𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Carbon-13 nuclear magnetic resonance spectra of methyl 2-pyronecarboxylates

✍ Scribed by Takeshi Imagawa; Akira Haneda; Mituyosi Kawanisi


Publisher
John Wiley and Sons
Year
1980
Tongue
English
Weight
393 KB
Volume
13
Category
Article
ISSN
0749-1581

No coin nor oath required. For personal study only.

✦ Synopsis


Abstract

The ^13^C NMR spectra of methyl 2‐pyrone‐3‐, 4‐, 5‐ and 6‐carboxylates were studied and the substituent effects on the 2‐pyrone ring were compared with those of some model compounds. ^1^H NMR spectra were also recorded and discussed. The long range ^13^C, ^1^H coupling constants were obtained, discussed and proved useful in signal assignments.


📜 SIMILAR VOLUMES


Carbon-13 nuclear magnetic resonance spe
✍ Deanna de Marcano; Bernardo Méndez; Henry Parada; Aníbal Rojas 📂 Article 📅 1981 🏛 John Wiley and Sons 🌐 English ⚖ 114 KB 👁 1 views

## Abstract The ^13^C NMR spectra were determined and signals assigned to the various carbons of veratridine and cevadine.

Carbon-13 nuclear magnetic resonance spe
✍ Francis A. Carey; William C. Hutton; James C. Schmidt 📂 Article 📅 1980 🏛 John Wiley and Sons 🌐 English ⚖ 402 KB

## Abstract The ^13^C NMR spectra were determined and signals assigned to the various carbons of the alkamines veracevine, germine and zygacine derived from steroidal alkaloids of the ceveratrum class. Assignment of signals was aided by analysis of the partially relaxed spectrum of cervagenine 9,12

Carbon-13 nuclear magnetic resonance spe
✍ A. J. de Hoog 📂 Article 📅 1974 🏛 John Wiley and Sons 🌐 English ⚖ 314 KB

## Abstract Fourier transform carbon‐13 nuclear magnetic resonance spectra have been obtained and interpreted for some 2‐substituted tetrahydropyrans. The effects of the substituents on α, β, γ and δ‐carbon atoms are discussed. Using suitable reference compounds the γ‐parameter can be used for quan

Carbon-13 nuclear magnetic resonance spe
✍ Kazuaki Isomura; Hiroshi Taniguchi; Masaaki Mishima; Mizue Fujio; Yuho Tsuno 📂 Article 📅 1977 🏛 John Wiley and Sons 🌐 English ⚖ 340 KB

## Abstract Carbon‐13 n.m.r. spectra have been obtained for some methyl and phenyl substituted 2__H__‐azirines. The higher field resonance of C‐2 than that of the corresponding aziridine carbon is interpreted in terms of ring strain. Substituent effects on the chemical shifts of the azirine ring ca

Carbon-13 nuclear magnetic resonance spe
✍ Deanna Marcano; Anibal Rojas; Bernardo Méndez; Jeannette De Méndez 📂 Article 📅 1981 🏛 John Wiley and Sons 🌐 English ⚖ 347 KB 👁 1 views

## Abstract The ^13^C chemical shift data of a series of ketone, alcohol and ester derivatives of D‐homoandrostane are reported. Homologation effects are discussed, as well as substituent effects on the homologated structures.

Carbon-13 nuclear magnetic resonance spe
✍ Deanna Marcano; Jeannette De Méndez; Ana C. Ortiz; Mirna Salinas 📂 Article 📅 1984 🏛 John Wiley and Sons 🌐 English ⚖ 277 KB 👁 1 views

REFERENCE DATA causes the electron density to be comparatively lower at C-3 and C-5 than at C-2 and C-4, so that the former signals resonate at lower fields. Distinction between the signals of the C-2/C-4 and C-3/C-5 pairs was achieved by comparing the C-H coupling patterns of 5 and 1. Compounds 1,