## Abstract Carbon‐13 n.m.r. spectra have been obtained for some methyl and phenyl substituted 2__H__‐azirines. The higher field resonance of C‐2 than that of the corresponding aziridine carbon is interpreted in terms of ring strain. Substituent effects on the chemical shifts of the azirine ring ca
Carbon-13 nuclear magnetic resonance spectra of some 2-substituted tetrahydropyrans
✍ Scribed by A. J. de Hoog
- Publisher
- John Wiley and Sons
- Year
- 1974
- Tongue
- English
- Weight
- 314 KB
- Volume
- 6
- Category
- Article
- ISSN
- 0749-1581
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✦ Synopsis
Abstract
Fourier transform carbon‐13 nuclear magnetic resonance spectra have been obtained and interpreted for some 2‐substituted tetrahydropyrans. The effects of the substituents on α, β, γ and δ‐carbon atoms are discussed. Using suitable reference compounds the γ‐parameter can be used for quantitative conformational analysis.
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REFERENCE DATA causes the electron density to be comparatively lower at C-3 and C-5 than at C-2 and C-4, so that the former signals resonate at lower fields. Distinction between the signals of the C-2/C-4 and C-3/C-5 pairs was achieved by comparing the C-H coupling patterns of 5 and 1. Compounds 1,
## Abstract The ^13^C NMR spectra of methyl 2‐pyrone‐3‐, 4‐, 5‐ and 6‐carboxylates were studied and the substituent effects on the 2‐pyrone ring were compared with those of some model compounds. ^1^H NMR spectra were also recorded and discussed. The long range ^13^C, ^1^H coupling constants were ob
## Abstract The ^13^C NMR spectra were determined and signals assigned to the various carbons of veratridine and cevadine.
## Abstract The ^13^C NMR spectra were determined and signals assigned to the various carbons of the alkamines veracevine, germine and zygacine derived from steroidal alkaloids of the ceveratrum class. Assignment of signals was aided by analysis of the partially relaxed spectrum of cervagenine 9,12