REFERENCE DATA causes the electron density to be comparatively lower at C-3 and C-5 than at C-2 and C-4, so that the former signals resonate at lower fields. Distinction between the signals of the C-2/C-4 and C-3/C-5 pairs was achieved by comparing the C-H coupling patterns of 5 and 1. Compounds 1,
Carbon-13 nuclear magnetic resonance spectra of D-homoandrostane derivatives
✍ Scribed by Deanna Marcano; Anibal Rojas; Bernardo Méndez; Jeannette De Méndez
- Publisher
- John Wiley and Sons
- Year
- 1981
- Tongue
- English
- Weight
- 347 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0749-1581
No coin nor oath required. For personal study only.
✦ Synopsis
Abstract
The ^13^C chemical shift data of a series of ketone, alcohol and ester derivatives of D‐homoandrostane are reported. Homologation effects are discussed, as well as substituent effects on the homologated structures.
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