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Carbon-13 nuclear magnetic resonance spectra of aminocyclohexanecarbonitriles and comparison with phencyclidine analogues

✍ Scribed by Keith Bailey; Donald Legault

Publisher
John Wiley and Sons
Year
1981
Tongue
English
Weight
395 KB
Volume
15
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

The ^13^C NMR spectra of 20 aminocycloalkanecarbonitriles were determined in CDCl~3~. The signals were assigned by a self‐consistent analysis of chemical shift data and comparison with results from phencyclidine analogues. The results were interpreted in terms of changes in the amine (primary, secondary, tertiary) and the cycloakane (cyclohexane vs cyclopentane) moieties and their bulk. Changes in the conformational equilibria of the cyclohexane series are suggested by comparisons between data from the carbonitrile and phencyclidine series. The spectra are suitable for corroborative authentication of reference materials and the identification of unknowns.

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