## Abstract The ^13^C chemical shifts of the diazanaphthalenes have been recorded as a function of the pH value, providing classical titration curves. From these curves the p__K__~1~ and p__K__~2~ values have been determined taking into account the activity coefficients. The changes in ^13^C chemic
Carbon-13 n.m.r. investigation on the nitrogen methylation of the mono- and diazanaphthalenes
✍ Scribed by Peter van de Weijer; (the late) Chandra Mohan; Dirk M. W. van den Ham
- Publisher
- John Wiley and Sons
- Year
- 1977
- Tongue
- English
- Weight
- 394 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0749-1581
No coin nor oath required. For personal study only.
✦ Synopsis
Abstract
The ^13^C n.m.r. spectra of the N‐methylated mono‐ and diazanaphthalenes have been recorded and analysed. It has been shown that N‐methylation as well as N‐protonation in cinnoline occur predominantly at the β‐nitrogen atom. N‐methylation and N‐protonation show a similar effect on the ^13^C chemical shifts.
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