## Abstract An alternative explanation for δ‐__syn__‐axial substituent effects of ^13^C chemical shifts is given using the concept that the δ‐__syn__‐axial interaction in the substituted compound replaces the γ‐__gauche__ interaction in the parent molecule. The application of this principle to subs
Substituent effect of the nitro group on alkanes in carbon-13 n.m.r. spectroscopy
✍ Scribed by Andrezej Ejchart
- Publisher
- John Wiley and Sons
- Year
- 1977
- Tongue
- English
- Weight
- 143 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0749-1581
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✦ Synopsis
Abstract
Linear correlation coefficients were obtained for the substituent effect of the nitro group in primary nitroalkanes. The solvent effect of chloroform is also discussed, as well as the influence of the scalar relaxation on the half‐width of α‐carbons in ^13^C n.m.r. spectroscopy.
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