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Carbon-13 n.m.r. of the 8-phosphabicyclo[3.2.1]octane system

✍ Scribed by A. Rudi; Y. Kashman

Publisher
John Wiley and Sons
Year
1977
Tongue
English
Weight
319 KB
Volume
10
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

^13^C Chemical shifts and ^13^C^31^P nuclear spin coupling constants have been determined for 26 8‐phosphabicyclo[3.2.1]octane derivatives, namely phosphines, phosphine oxides, phosphine sulphides and one phosphonium salt. The influence of the phosphorus configuration on δ and ^2^J(PC) values was examined and other factors influencing the ^2^J(PC) coupling constant are discussed.

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