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Carbon-13 and proton EPR analysis of the benzo[a]pyrene cation

โœ Scribed by Sullivan, Paul D.; Bannoura, Fouad; Daub, Guido H.


Book ID
127074332
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
516 KB
Volume
107
Category
Article
ISSN
0002-7863

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13C labeled benzo[a]pyrenes and derivati
โœ J. Ernest Simpson; Guido H. Daub; David L. Vanderjagt ๐Ÿ“‚ Article ๐Ÿ“… 1980 ๐Ÿ› John Wiley and Sons ๐ŸŒ French โš– 240 KB

## Abstract The synthesis of benzo[a]pyreneโ€6โ€^13^C is described. Perinaphthane was converted to 6โ€benzoylโ€carbonylโ€^13^Cโ€perinaphthane which was cyclized to 2,3โ€dihydrobenzo[a]pyrenโ€6(1H)โ€oneโ€6โ€^13^C. Subsequent reduction of the ketone followed by dehydration and dehydrogenation gave benzo[a]pyren