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EPR Studies of 13C-labeled and monomethylated 6-oxybenzo[α]pyrene and 6-trifluoroacetoxy-benzo[a]pyrene radicals

✍ Scribed by Xinhua Chen; Fouad Bannoura; Paul D Sullivan


Publisher
Elsevier Science
Year
1987
Weight
840 KB
Volume
75
Category
Article
ISSN
0022-2364

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📜 SIMILAR VOLUMES


13C labeled benzo[a]pyrenes and derivati
✍ J. Ernest Simpson; Guido H. Daub; David L. Vanderjagt 📂 Article 📅 1980 🏛 John Wiley and Sons 🌐 French ⚖ 240 KB

## Abstract The synthesis of benzo[a]pyrene‐6‐^13^C is described. Perinaphthane was converted to 6‐benzoyl‐carbonyl‐^13^C‐perinaphthane which was cyclized to 2,3‐dihydrobenzo[a]pyren‐6(1H)‐one‐6‐^13^C. Subsequent reduction of the ketone followed by dehydration and dehydrogenation gave benzo[a]pyren

Synthesis of 6-substituted benzo[a]pyren
✍ James L. Hicks; J. Richard Heys 📂 Article 📅 1981 🏛 John Wiley and Sons 🌐 French ⚖ 332 KB

## Abstract 6‐Lithiobenzo[__a__]pyrene was carbonated to produce benzo[__a__]pyrene‐6‐carboxylic‐^14^C acid, which was in turn used in the preparation of several derivatives. Methylation to the ester was followed by LiAlH~4~ reduction to 6‐hydroxymethyl‐^14^C‐benzo[__a__]pyrene. An efficient oxidat