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Bis­[μ-bis(2,6-di-1-naphthyl­phenyl)­phosphanido]­bis­[(tetra­hydro­furan)­sodium(I)]

✍ Scribed by Rabe, Gerd W. ;Riederer, Florian A. ;Incarvito, Christopher D. ;Golen, James A. ;Rheingold, Arnold L.


Publisher
International Union of Crystallography
Year
2004
Tongue
English
Weight
451 KB
Volume
60
Category
Article
ISSN
1600-5368

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📜 SIMILAR VOLUMES


Bis­[μ2-bis­(di­phenyl­phosphinoyl)­meth
✍ Nassar, Roger ;Noll, Bruce C. ;Henderson, Kenneth W. 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 210 KB

The title centrosymmetric alumoxane compound, [Al 4 -(CH 3 ) 6 (" 3 -O) 2 ("-{Ph 2 P(O)} 2 CH) 2 ]ÁC 4 H 8 O, is dimeric in the solid state as its THF disolvate, with a central Al 2 O 2 ring core connected to terminal Me 2 Al units through oxo and nonchelating phosphinate anions.

[1,2-Bis­(di­phenyl­phosphino)­ethane]­d
✍ Beaudoin, Sophie ;Zargarian, Davit ;Bélanger-Gariépy, Francine ;Fontaine, Frédér 📂 Article 📅 2001 🏛 International Union of Crystallography 🌐 English ⚖ 269 KB

Acta Cryst. (2001). E57, m433±m434 slightly longer in the THF adduct than the corresponding distances in the CH 2 Cl 2 adduct [2.141 (1) and 2.156 (1) A Ê ], but both NiÐBr bonds are very similar. In this structure, there is a stacking interaction between the THF ring and the C121Ð C126 phenyl ring,