Bis[μ-bis(2,6-di-1-naphthylphenyl)phosphanido]bis[(tetrahydrofuran)sodium(I)]
✍ Scribed by Rabe, Gerd W. ;Riederer, Florian A. ;Incarvito, Christopher D. ;Golen, James A. ;Rheingold, Arnold L.
- Publisher
- International Union of Crystallography
- Year
- 2004
- Tongue
- English
- Weight
- 451 KB
- Volume
- 60
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The title centrosymmetric alumoxane compound, [Al 4 -(CH 3 ) 6 (" 3 -O) 2 ("-{Ph 2 P(O)} 2 CH) 2 ]ÁC 4 H 8 O, is dimeric in the solid state as its THF disolvate, with a central Al 2 O 2 ring core connected to terminal Me 2 Al units through oxo and nonchelating phosphinate anions.
Acta Cryst. (2001). E57, m433±m434 slightly longer in the THF adduct than the corresponding distances in the CH 2 Cl 2 adduct [2.141 (1) and 2.156 (1) A Ê ], but both NiÐBr bonds are very similar. In this structure, there is a stacking interaction between the THF ring and the C121Ð C126 phenyl ring,