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Bis(μ-2,2′′-di­methoxy-m-ter­phenyl)­di-μ3-iodo-bis­(tetra­hydro­furan)­tetralithium(I)

✍ Scribed by Rabe, Gerd W. ;Zhang-Preße, Mei ;Yap, Glenn P. A.

Publisher
International Union of Crystallography
Year
2002
Tongue
English
Weight
239 KB
Volume
58
Category
Article
ISSN
1600-5368

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✍ Nassar, Roger ;Noll, Bruce C. ;Henderson, Kenneth W. 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 210 KB

The title centrosymmetric alumoxane compound, [Al 4 -(CH 3 ) 6 (" 3 -O) 2 ("-{Ph 2 P(O)} 2 CH) 2 ]ÁC 4 H 8 O, is dimeric in the solid state as its THF disolvate, with a central Al 2 O 2 ring core connected to terminal Me 2 Al units through oxo and nonchelating phosphinate anions.