The dinuclear Fe^III^ complex in the title compound, [Fe~2~Cl~2~O(C~18~H~18~N~4~)~2~](PF~6~)~2~, lies on a center of inversion. The Fe^III^ atom is chelated by a tetradentate tris(2-pyridylmethyl)amine ligand __via__ four N atoms and further coordinated by one chloride ion and one bridging oxide O a
Bis[tris(2-ammonioethyl)amine] bis(pentafluoridooxidomolybdate) difluoride monohydrate
✍ Scribed by Adil, K. ;Marrot, J. ;Leblanc, M. ;Maisonneuve, V.
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 267 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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Single-crystal X-ray study T = 295 K Mean '(C±C) = 0.003 A Ê R factor = 0.037 wR factor = 0.105 Data-to-parameter ratio = 15.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the title complex, [Mn(C 24 H 27 N 7 )](ClO 4 ) 2 , the Mn II ion is chelated by a tris [2-(2-pyridylmethyleneimino)ethyl]amine ligand, in a distorted octahedral coordination geometry. Weak C-HÁ Á ÁO interactions occur between the perchlorate anions and the Mn II complex cation. metal-organic pap
In the title structure, [Cu(C~24~H~21~N~7~)(H~2~O)](ClO~4~)~2~·C~5~H~4~N~2~O~3~·H~2~O, the Cu^II^ atom is bonded to a tris(1__H__-benzimidazol-2-ylmethyl)amine (ntb) ligand and a water molecule through four N atoms and one O atom, giving a distorted trigonal–bipyramidal coordination geometry with ap