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Bis(triphenylphosphine oxide)hydronium tetrachloroaurate(III)

✍ Scribed by Jones, P. G. ;Sheldrick, G. M.


Book ID
114525066
Publisher
International Union of Crystallography
Year
1978
Weight
292 KB
Volume
34
Category
Article
ISSN
0567-7408

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Tetrachloroaurate(III) oxidation of thal
✍ Anna N. Gidd; Madhukar D. Bhand; Gavisiddappa S. Gokavi 📂 Article 📅 1995 🏛 Springer 🌐 English ⚖ 182 KB

The complementary reaction between T1 t and AuC12 was studied in a 3.0 mol dm-3 HC1 medium. The active species of oxidant and reductant were found to be HAuCI+ and T1C12, respectively. A mechanism involving these reactive species is proposed, in agreement with the results obtained.