Di-μ-iodo-bis[diiodobis(triphenylphosphine oxide)bismuth(III)]
✍ Scribed by Lazarini, F. ;Milićev, S.
- Book ID
- 117860086
- Publisher
- International Union of Crystallography
- Year
- 1976
- Weight
- 355 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0567-7408
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📜 SIMILAR VOLUMES
The title salt, (C 4 H 12 N 2 ) 2 [Bi 2 Cl 10 ]Á3H 2 O, was prepared by reaction of bismuth trichloride and piperazine in a hydrochloric acid medium. It consists of piperazinium dications and dimeric [Bi 2 Cl 10 ] 4À tetraanions, the latter with twofold rotation symmetry, together with water of crys
In the title compound, (C 5 H 14 N 2 ) 2 [Bi 2 Cl 10 ]Á2H 2 O, each Bi III atom of the centrosymmetric anion is six-coordinate in a distorted octahedral geometry. The salt adopts a threedimensional network arising from the hydrogen bonds between the cations, anions and water molecules.