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Bis(trimethylsilyl) trimethylsilyloxymethylphosphonite: a useful reagent for the introduction of the hydroxymethylphosphinate group

✍ Scribed by Rosenthal, Arthur F.; Gringauz, Alex; Vargas, Luis A.

Book ID
121693904
Publisher
The Royal Society of Chemistry
Year
1976
Tongue
English
Weight
135 KB
Volume
11
Category
Article
ISSN
0022-4936

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πŸ“œ SIMILAR VOLUMES

Trimethylsilyl polyphosphate (PPSE), a u
Trimethylsilyl polyphosphate (PPSE), a useful reagent for the beckmamn rearrangement
✍ Tsuneo Imamoto; Hideki Yokoyama; Masataka Yokoyama πŸ“‚ Article πŸ“… 1981 πŸ› Elsevier Science 🌐 French βš– 140 KB

Various oximea were rearranged smoothly to the corresponding amides in trimethylailyl polyphoaphate (PPSE) which was conveniently prepared from phosphorus pentoxide and hexamethyldiailoxane.

Bis(trimethylsilyl)peroxide as a versati
Bis(trimethylsilyl)peroxide as a versatile reagent for selective generation of oxyphosphoryl group
✍ L. WoΕΊniak; J. Kowalski; J. Chojnowski πŸ“‚ Article πŸ“… 1985 πŸ› Elsevier Science 🌐 French βš– 240 KB

Bis(trimethylsilyl)peroxide, Me3SiOOSiMe3, ( ) BSPO oxidizes phosphines and phosphites to respective oxyphosphoryl derivatives with retention of the configuration at the phosphorus atom. It also converts thiophosphoryl function to oxyphosphoryl function with inversion of the configuration at phospho