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Trimethylsilyl polyphosphate (PPSE), a useful reagent for the beckmamn rearrangement

✍ Scribed by Tsuneo Imamoto; Hideki Yokoyama; Masataka Yokoyama

Book ID: 104241639
Publisher: Elsevier Science
Year: 1981
Tongue: French
Weight: 140 KB
Volume: 22
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)90444-7

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✦ Synopsis

Various oximea were rearranged smoothly to the corresponding amides in trimethylailyl polyphoaphate (PPSE) which was conveniently prepared from phosphorus pentoxide and hexamethyldiailoxane.

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