Bis(trimethylphosphine-κP)gold(I) hexafluorophosphate
✍ Scribed by Horvath, Ulrike E. I. ;Raubenheimer, Helgard G.
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 125 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 295 K Mean (C-C) = 0.007 A R factor = 0.038 wR factor = 0.102 Data-to-parameter ratio = 21.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title compound, [Cu 2 (" 2 -dppm) 2 (MeCN) 4 ](PF 6 ) 2 or [Cu 2 (C 25 H 22 P 2 ) 2 (C 2 H 3 N) 4 ](PF 6 ) 2 , crystallizes in the monoclinic space group C2/c, with the cation on a twofold axis. The Cu centers are four-coordinated, exhibiting pseudo-tetrahedral coordination.
In the title compound, [RuCl(C~26~H~24~P)~2~(H~2~O)]PF~6~·1.5CH~2~Cl~2~·0.5H~2~O, the complex Ru^II^ cation is in a slightly distorted octahedral environment, chelated by two bis(diphenylphosphino)ethane ligands, with a water molecule and a chloride anion in a mutually __cis__ geometry completing th