Bis[iodidobis(1,10-phenanthroline-κ2N,N′)copper(II)] tetraiodidocadmate(II)
✍ Scribed by Cao, Ming-Lei ;Fang, Xin ;Zhang, Yan-Jun ;Yu, Hai-Yang ;Wang, Jun-Dong
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 497 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
Bis[iodidobis(1,10-phenanthroline-2 N,N')copper(II)] tetraiodidocadmate(II)
📜 SIMILAR VOLUMES
The title mononuclear complex, [Cu(C 2 H 3 O 3 ) 2 (C 12 H 8 N 2 )]Á-2H 2 O, is isostructural with its zinc(II) analogue. The Cu atom in the complex exists in a distorted octahedral coordination environment, defined by four O atoms and two N atoms. O-HÁ Á ÁO hydrogen bonds andstacking interactions h
The crystal structure of the title compound, [CuCl 2 -(C 14 H 12 N 2 )(H 2 O)], previously reported by Preston & Kennard [J. Chem. Soc. A (1969). pp. 2955±2958], has been redetermined. The recognition of an inversion twin allowed a much better re®nement.