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[Bis­(di­phenyl­phosphino)­methane][μ,η2-bis­(tri­methyl­stannyl)­acetyl­ene]­tetra­carbonyl­dicobalt

✍ Scribed by Zachwieja, Uwe ;Preut, Hans ;Mitchell, Terence ;Zavgorodnii, Vladislav S. ;Golosovskii, Andrei V. ;Karpov, Maxim G.


Publisher
International Union of Crystallography
Year
2001
Tongue
English
Weight
234 KB
Volume
57
Category
Article
ISSN
1600-5368

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📜 SIMILAR VOLUMES


{[μ,η2-Bis­(tri­methyl­stannyl)]­acetyl­
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Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.005 A Ê R factor = 0.034 wR factor = 0.091 Data-to-parameter ratio = 21.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

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Single-crystal X-ray study T = 200 K Mean '(C±C) = 0.012 A Ê R factor = 0.022 wR factor = 0.025 Data-to-parameter ratio = 10.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

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The title compound, [Cu 2 (" 2 -dppm) 2 (MeCN) 4 ](PF 6 ) 2 or [Cu 2 (C 25 H 22 P 2 ) 2 (C 2 H 3 N) 4 ](PF 6 ) 2 , crystallizes in the monoclinic space group C2/c, with the cation on a twofold axis. The Cu centers are four-coordinated, exhibiting pseudo-tetrahedral coordination.

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Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.026 A Ê R factor = 0.066 wR factor = 0.160 Data-to-parameter ratio = 14.5 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.