✦ LIBER ✦

Bis[chloridobis(triphenylphosphine)copper(I)-μ-chlorido]bis(1,2-diaminopropane)copper(II) acetonitrile disolvate

✍ Scribed by Habibi, Mohammad Hossein ;Mikhak, Maryam ;Harrington, Ross W. ;Clegg, William

Publisher: International Union of Crystallography
Year: 2007
Tongue: English
Weight: 774 KB
Volume: 63
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536807037282

No coin nor oath required. For personal study only.

✦ Synopsis

The title complex [systematic name: bis(1,2-diaminopropane-2 2 N,N 0 )di--chlorido-1:2 2 Cl,2:3 2 Cl-dichlorido-1Cl,3Cltetrakis(triphenylphosphine)-1 2 P,3 2 P-tricopper(I,II,I) acetonitrile disolvate], [{(Ph 3 P) 2 Cl 2 Cu} 2 Cu(C 3 H 10 N 2 ) 2 ]Á2C 2 H 3 N, is a centrosymmetric linear trinuclear mixed-valence copper complex in which the central Cu II atom is bridged by Cl atoms to the two Cu I atoms. The coordination geometry is octahedral for Cu II , with Jahn-Teller elongation of the Cu-Cl bonds, and distorted tetrahedral for Cu I , with a wide P-Cu-P angle. The diamine ligands are twofold disordered, with occupancy factors of ca 0.6:0.4, and form one N-HÁ Á ÁCl hydrogen bond each with a terminal Cl atom.

📜 SIMILAR VOLUMES

Poly[[bis(acetonitrile-κN)bis{μ-2-[(2-

Poly[[bis(acetonitrile-κN)bis{μ-2-[(2-carboxylatoethyl)ammoniomethyl]benzoato}copper(II)] bis(perchlorate) acetonitrile disolvate]

✍ Musie, Ghezai T. ;Li, Xiaobao ;Klausmeyer, Kevin K. 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 179 KB

{μ-Bis[1-(pyridin-2-yl)ethylidene]etha

{μ-Bis[1-(pyridin-2-yl)ethylidene]ethane-1,2-diamine-κ2N,N′}bis[iodo(triphenylphosphine-κP)copper(I)] acetonitrile disolvate

✍ Khalajii, Aliakbar Dehno ;Amirnasr, Medhi ;Welter, Richard 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 131 KB

{l-Bis [1-(pyridin-2-yl)ethylidene]ethane-1,2-diamine-j 2 N,N 0 0 0 }bis[iodo(triphenylphosphine-jP)copper(I)] acetonitrile disolvate

Di-μ-chlorido-bis[(2-anilinobenzoato-κ2O

Di-μ-chlorido-bis[(2-anilinobenzoato-κ2O,O′)(1,10-phenanthroline-κ2N,N′)copper(II)]

✍ Jiang, Hui ;Ma, Jian-Fang ;Zhang, Wen-Li 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 804 KB

Di-l-chlorido-bis[(2-anilinobenzoatoj 2 O,O 0 0 0 )(1,10-phenanthroline-j 2 N,N 0 0 0 )copper(II)]

Di-μ-thiocyanato-bis{[1,1′-bis(diphe

Di-μ-thiocyanato-bis{[1,1′-bis(diphenylphosphino)ferrocene-κ2P,P′]copper(I)} dichloromethane disolvate

✍ Li, Dan ;Luo, Ya-Fang ;Wu, Tao ;Ng, Seik Weng 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 225 KB

Single-crystal X-ray study T = 123 K Mean '(C±C) = 0.007 A Ê Disorder in solvent or counterion R factor = 0.056 wR factor = 0.166 Data-to-parameter ratio = 17.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

Bis[μ-bis(diphenylphosphino)methane-κ2

Bis[μ-bis(diphenylphosphino)methane-κ2P:P′]bis[(1,10-phenanthroline-κ2N,N′)copper(I)] bis(tetrafluoroborate) dichloromethane disolvate

✍ Liu, Huan-Yu ;Wang, Fen-Ying ;Wang, Guo-Yong ;Huang, Chang-Gan ;Peng, Da-Yong 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 160 KB

Bis[l-bis(diphenylphosphino)methane-j 2 P:P 0 0 0 ]bis[(1,10-phenanthroline-j 2 N,N 0 0 0 )copper(I)] bis(tetrafluoroborate) dichloromethane disolvate

μ-1,2-Ethanediylbis(diphenylphosphine)-

μ-1,2-Ethanediylbis(diphenylphosphine)-κ2P:P′-bis{acetato[1,2-ethanediylbis(diphenylphosphine)-κ2P,P′]copper(I)} diethyl ether disolvate

✍ Morawitz, Thorsten ;Lerner, Hans-Wolfram ;Bru Roig, Miriam ;Bolte, Michael 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 176 KB