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Bis[benzyl(methyl)ammonium] tetrathiomolybdate(VI)

✍ Scribed by Srinivasan, Bikshandarkoil R. ;Girkar, Siddhali V. ;Raghavaiah, Pallepogu

Publisher: International Union of Crystallography
Year: 2007
Tongue: English
Weight: 751 KB
Volume: 63
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536807049562

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✦ Synopsis

The title compound, (C~8~H~12~N)~2~[MoS~4~], was synthesized by the aqueous reaction of ammonium tetrathiomolybdate with benzyl(methyl)amine in a 1:2 molar ratio. The structure consists of a slightly distorted tetrahedral [MoS~4~]^2−^ dianion and two crystallographically independent benzyl(methyl)ammonium cations, with all atoms located in general positions. The cations and anions are linked by weak N—H...S and C—H...S interactions, the strength and number of which can explain the observed Mo—S bond distances.

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