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Bis­(benzyl­tri­methyl­ammonium) tetra­chloro­nickelate(II) N-methyl­pyrrolidin-2-one solvate

✍ Scribed by Kooijman, Huub ;Keegstra, Menno A. ;Brandsma, Lambert ;Spek, Anthony L.

Publisher
International Union of Crystallography
Year
2004
Tongue
English
Weight
334 KB
Volume
60
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, (C 10 H 16 N) 2 [NiCl 4 ]ÁC 5 H 9 NO, was obtained as a side-product in a reaction of PhNiCl(PPh 3 ) 2 with quaternary ammonium ions in N-methylpyrrolidin-2-one. CÐHÁ Á ÁCl interactions link the ions into two-dimensional networks parallel to the bc plane.

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✍ Raimondi, Angela Cristina ;Hasegawa, Tai ;Nunes, Fábio Souza 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 174 KB

The title complex, (C 6 H 18 N 2 )[V 2 Cl 5 (C 6 H 16 N 2 ) 2 ](C 24 H 20 B).-C 4 H 8 O, was prepared by the reaction of [V 2 Cl 3 (THF) 6 ](BPh 4 ) with [FeCl 2 (tmeda) 2 ] in the presence of one equivalent of tmeda (tmeda = N,N,N H ,N H -tetramethylethylenediamine) in methanol. The crystal structu