The title compound, C~52~H~66~N~6~O~4~·2CH~3~OH, is a 5,15-diaryloctaalkylporphyrinogen. The molecule is centrosymmetric, with the pyrrole rings adopting a 1,2-alternate arrangement. The methanol molecules are included in the tetrapyrrole cavity through hydrogen bonding and O—H...π interactions. The
[5,15-Bis(4-pyridyl)-2,8,12,18-tetra-n-butyl-3,7,13,17-tetramethylporphyrinato]zinc(II) chloroform solvate
✍ Scribed by Wild, Kirstie Y. ;Therrien, Bruno ;Plieger, Paul G. ;Officer, David L. ;Burrell, Anthony K.
- Publisher
- International Union of Crystallography
- Year
- 2001
- Tongue
- English
- Weight
- 336 KB
- Volume
- 57
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
Single-crystal synchrotron study T = 150 K Mean '(C±C) = 0.003 A Ê R factor = 0.052 wR factor = 0.129 Data-to-parameter ratio = 23.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title compound, C~59~H~64~CuN~5~O~3~·C~6~H~6~, features an essentially planar porphyrin ring system, with the Cu atom located in the plane and showing equal Cu—N distances. The space between the molecules is occupied by benzene solvent molecules.
The structure of the title compound, [Zn(C 92 H 60 N 4 )-(C 2 H 3 N)]ÁC 2 H 3 N, shows relatively small saddle-type distortion with ruf¯ing, compared to other dodecaphenylporphyrin complexes.
Single-crystal synchrotron study T = 160 K Mean '(C±C) = 0.004 A Ê Disorder in main residue R factor = 0.054 wR factor = 0.135 Data-to-parameter ratio = 16.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
A new heterotrinuclear macrocyclic complex: bis (ldiethyl 5,6,7,8,15,16-hexahydro-6,7-dioxo-5,8,14,17tetraazadibenzo[a,g]cyclotetradecine-13,18dicarboxylato)-1j 4 N:2j 2 O 6 ,O 7 ;2jO 6 ,O 7 :3j 4 Ndimethanoldinickel(II)zinc(II) bis(perchlorate)