{5-[4′-(2,2,5,5-Tetramethyl-3-pyrroline-1-oxyl-3-carbonyl)biphenyl-4-ylethynyl]-2,3,7,8,12,13,17,18-octaethylporphyrinato}copper(II) benzene solvate
✍ Scribed by Bolte, Michael
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 223 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The title compound, C~59~H~64~CuN~5~O~3~·C~6~H~6~, features an essentially planar porphyrin ring system, with the Cu atom located in the plane and showing equal Cu—N distances. The space between the molecules is occupied by benzene solvent molecules.
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Single-crystal synchrotron study T = 150 K Mean '(C±C) = 0.003 A Ê R factor = 0.052 wR factor = 0.129 Data-to-parameter ratio = 23.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Single-crystal synchrotron study T = 160 K Mean '(C±C) = 0.004 A Ê Disorder in main residue R factor = 0.054 wR factor = 0.135 Data-to-parameter ratio = 16.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
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