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2,8,12,18-Tetra­butyl-3,7,13,17-tetra­methyl-5,15-bis­(3-nitro­phen­yl)porphyrinogen methanol disolvate

✍ Scribed by Boyd, Peter D. W. ;Hosseini, Ali ;Rickard, Clifton E. F.

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
247 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, C~52~H~66~N~6~O~4~·2CH~3~OH, is a 5,15-diaryloctaalkylporphyrinogen. The molecule is centrosymmetric, with the pyrrole rings adopting a 1,2-alternate arrangement. The methanol molecules are included in the tetrapyrrole cavity through hydrogen bonding and O—H...π interactions. The molecules form chains in the crystal structure via phenyl C—H...π-pyrrole stacking.

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