Di-l-chloro-bis[chloro(dipyridophenazinej 2 N,N 0 0 0 )copper(II)]
Bis(5-chloro-N-isopropylsalicyldenaminato-κ2N,O)copper(II)
✍ Scribed by Akitsu, Takashiro ;Einaga, Yasuaki
- Publisher
- International Union of Crystallography
- Year
- 2004
- Tongue
- English
- Weight
- 220 KB
- Volume
- 60
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
The polymeric structure of the title complex, [Cu(C~7~H~4~ClO~3~)~2~(C~6~H~7~NO)~2~]~__n__~, at 100 (2) K contains two-dimensional sheets parallel to the __ac__ plane. The Cu^II^ atom, lying on an inversion centre, has an octahedral coordination environment. It is bonded in a __trans__-square-planar
Figure 1 ORTEP-3 (Farrugia, 1997) view of (I), with 50% probability displacement ellipsoids. H atoms are shown as spheres with arbitrary radii. metal-organic papers m902 Victor B. Rybakov et al. [CuCl 2 (C 20 H 18 N 2 O 2 )] Acta Cryst. (2004). E60, m901±m903
In the title dimeric complex, [Cu~2~(C~2~O~4~)Cl~2~(C~12~H~8~N~2~)~2~], which lies on a crystallographic inversion center, the Cu^II^ ion is in a distorted trigonal–bipyramidal coordination geometry formed by two N atoms from a phen ligand, two O atoms from a bridging oxalate ligand and one Cl atom.
The title compound, [CuCl 2 (C 10 H 8 N 2 )], has twofold symmetry and the coordination geometry around the Cu II atom is distorted square-planar. There are weak intermolecular CuÁ Á ÁCl interactions, forming a chain structure in the crystal.
The title complex, [Cu 2 (N 3 ) 4 (C 5 H 14 N 2 ) 2 ], is a centrosymmetric dimer in which each Cu atom is coordinated by five N atoms from three azide anions and one N,N-dimethyl-1,3-propylenediamine molecule in a distorted square-pyramidal geometry; the CuÁ Á ÁCu distance is 3.416 (1) A ˚.