In the title compound, C 14 H 22 N 4 S 2 , a diethyl disul®de bridge containing an SÐS bond of 2.0396 (6) A Ê connects two 3,5dimethylpyrazole rings via the N1 atoms. The disul®de molecules are linked by weak CÐHÁ Á Á%(pyrazole) interactions into chains that propagate along the b direction.
✦ LIBER ✦
Bis(3,5-dimethylpyrazol-1-yl)acyl and Bis(3,5-dimethylpyrazol-1-yl)methide Carbonyl Tungsten Derivatives
✍ Scribed by Xie, Yun-Fu; Wen, Zhen-Kang; Tan, Run-Yu; Hong, Juan; Zhao, Shu-Bin; Tang, Liang-Fu
- Book ID
- 115496899
- Publisher
- American Chemical Society
- Year
- 2008
- Tongue
- English
- Weight
- 198 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0276-7333
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## Abstract Two novel complexes, [CuCl~2~(Mebdmpza)] (1) and [Cu~2~(μ‐O~4~C~2~)Cl~2~(Mebdmpza)~2~] (2) [Mebdmpza = methyl bis(3,5‐dimethylpyrazol‐1‐yl)acetate], were synthesized by reaction of CuCl~2~ with the precursor ligand bis(3,5‐dimethylpyrazol‐1‐yl)acetic acid (Hbdmpza) in methanol. The X‐ra