Ruthenium Nitrosyl Complexes of Bis(3,5-dimethylpyrazol-1-yl)methane Oxyanions
✍ Scribed by Mayreli Ortiz; Alicia Díaz; Roberto Cao; Reynier Suardíaz; Antonio Otero; Antonio Antiñolo; Juan Fernández-Baeza
- Publisher
- John Wiley and Sons
- Year
- 2004
- Tongue
- English
- Weight
- 140 KB
- Volume
- 2004
- Category
- Article
- ISSN
- 1434-1948
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## Abstract Two novel complexes, [CuCl~2~(Mebdmpza)] (1) and [Cu~2~(μ‐O~4~C~2~)Cl~2~(Mebdmpza)~2~] (2) [Mebdmpza = methyl bis(3,5‐dimethylpyrazol‐1‐yl)acetate], were synthesized by reaction of CuCl~2~ with the precursor ligand bis(3,5‐dimethylpyrazol‐1‐yl)acetic acid (Hbdmpza) in methanol. The X‐ra
## Abstract Six new ruthenium(II) complexes with the scorpionateligand bis(3,5‐dimethylpyrazol‐1‐yl)dithio‐κ^3^__N__,__N__,__S__‐acetate (bdmpzdta) were obtained by treatment of the ligand with RuCl~3~ or [RuCl~3~(NO)] in 1:1 or 2:1 molar ratios in the presence or absence of ethylenediamine. In all
## Abstract A series of ruthenium(II) complexes with the pyrazolylalkane ligands bis(pyrazol‐1‐yl)methane (BPM) (I) and bis(3,5‐dimethylpyrazol‐1‐yl)methane (dmBPM) (II), and the imidazolylalkane ligand bis(__N__‐methylimidazol‐2‐yl)methane (BIM) (III) have been synthesised and characterised. The c